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(Seminar) Mullins effect induced by chain de-lamination

09/11 2020
  • Title (Seminar) Mullins effect induced by chain de-lamination
  • Speaker
  • Date
  • Venue
  • Abstract

    CAS Key Laboratory of Theoretical Physics

    Institute of Theoretical Physics

    Chinese Academy of Sciences

    Seminar

    Title

    题目

    Mullins effect induced by chain de-lamination

    Speaker

    报告人

    钱道远

    Affiliation

    所在单位

    英国剑桥大学

    Date

    日期

    2020年9月11日(周五)16:00--17:00

    Venue

    地点

    南楼6420

    Contact Person

    所内联系人

    孟凡龙

    Abstract

    摘要

    we propose a new model to incorporate chain de-lamination and re-attachment processes in stretching filled rubber elastomers, which is then adapted to explain Mullins effect with partial recovery. The Mullins effect refers to the softening observed in pre-stretched filled rubber elastomers up to the maximum strain ever attained in the material’s history. In our model, Mullins softening is accounted for by allowing polymer chains to elongate upon stretching, and contract during relaxation, so the recovery effect is naturally included. At the heart of the model we promote the chain lengths, normally assumed to be constant, to variables that change with loading cycles. By fitting eight material parameters, namely the rubber and entanglement moduli, minimum chain length, de-lamination and re-attachment rate, two Log-Normal distribution parameters and an entanglement damage factor, we are able to achieve good agreement between numerical calculation results and experimental data at large stretches. It should be noted that this formalism is by no means restricted to explain Mullins effect and can be easily incorporated into more complex material models through, for example, network decomposition.